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Jon Hamm, Rihanna, Emma Stone, Kings of Leon on October SNL's

By April MacIntyre Oct 10, 2010, 3:07 GMT

Actors Elisabeth Moss (L) and Jon Hamm (R) of TV series Mad Men EPA/BRUNO

SNL returns with two back-to-back live shows starting on October 23rd with actress Emma Stone and musical guest Kings of Leon.  On October 30, host Jon Hamm is paired with musical guest Rihanna on NBC's "Saturday Night Live."

Most recently seen in the feature film comedy, "Easy A," Emma Stone is currently filming "The Help." Stone can next be seen opposite Steve Carell and Ryan Gosling in "Crazy, Stupid, Love" due out April 2011.

Kings of Leon will make their second musical guest appearance debuting new songs from their fifth studio album, “Come Around Sundown.”

Jon Hamm will serve as host for his third time on October 30. Hamm is the star of the award-winning AMC series "Mad Men," and currently can be seen alongside Ben Affleck, Blake Lively and Rebecca Hall in "The Town."

Grammy award-winner Rihanna will make her second musical guest appearance with performances from her soon to be released fifth studio album, “Loud.”